Remember a little while ago we told you that Angelina Jolie’s become the new face of Louis Vuitton? Here is the first ad to confirm. This is part of a campaign called “Core Values,” shot by Annie Leibovitz following other celebrities such as U2′s Bono, Sean Connery, Keith Richards, and Catherine Deneuve. It features the actress sitting on a wooden boat in Cambodia and a beautiful Louis Vuitton over her shoulder. All the money she makes through this will go to charity. Some brands need to start learning a thing or two from these big-hearted ones rather than chase poor, helpless animals.